Физико-химическое моделирование в нефтегазовой геохимии. Часть 2. Модели гетерогенных систем. Бычинский В.А - 52 стр.

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– 52 –
Òàáëèöà 2.8
Ðåçóëüòàòû ðàñ÷åòà ñòàáèëüíîãî ðàâíîâåñèÿ â ñèñòåìå Ca–Mg–C–H–O–e
è âûáîð ðàñ÷åòíûõ ïàðàìåòðîâ äëÿ ïîñëåäóþùèõ ìîäåëåé
Temperature, C 75.00 G, cal -3243396 Eh, B -0.1856
Pressure, bar 250.00 H, cal -3795086 pe -2.6917
Volume, cm^3 1033.600 S, cal/K 1097.879 pH 5.0238
Mass, kg 1.027 U, cal -3752219 Ion strength 0.1260
Density, g/cm^3 0.993490 Cp, cal 1010.21
Phase parameters:
name phase volume, cm^3 mole quantity mass, g weight %
Water 1028.81959 5.57904e+01 1013.1741 98.66609
Dol 4.78087 7.42808e-02 13.6975 1.33390
____________________________________________________________________________________________________________________________________________________________
Independent components:
chemical disparity dual chemical molality log mg/kgH2O
composition balance mass solution potential molality
C 0.8000000 2.2243e-09 6.88389 4763 6.548e-01 -0.184 7.865e+03
Ca 0.1000000 5.6813e-11 -182.88232 -126525 2.585e-02 -1.588 1.036e+03
Mg 0.1000000 1.3377e-09 -147.42732 -101996 2.585e-02 -1.588 6.283e+02
X 0.1300000 -1.5711e-13 9.26697 6411 1.307e-01 -0.884 0.000e+00
H 112.1119965 5.3163e-08 -5.36014 -3708 1.669e+00 0.222 1.682e+03
O 56.1159983 4.5614e-09 -72.36469 -50065 4.468e-01 -0.350 7.148e+03
e 0.0000e+00 1.9008e-13 -6.19768 -4288
                                                                                                                                        Òàáëèöà 2.8
                     Ðåçóëüòàòû ðàñ÷åòà ñòàáèëüíîãî ðàâíîâåñèÿ â ñèñòåìå Ca–Mg–C–H–O–e
                           è âûáîð ðàñ÷åòíûõ ïàðàìåòðîâ äëÿ ïîñëåäóþùèõ ìîäåëåé

Temperature, C    75.00                            G, cal            -3243396             Eh, B    -0.1856
Pressure, bar    250.00                           H, cal           -3795086            pe       -2.6917
Volume, cm^3    1033.600                          S, cal/K          1097.879           pH        5.0238
Mass, kg           1.027                          U, cal           -3752219            Ion strength     0.1260
Density, g/cm^3    0.993490                       Cp, cal           1010.21

Phase parameters:
name phase   volume, cm^3                      mole quantity                 mass, g            weight %




                                                                                                                                                               – 52 –
Water                   1028.81959               5.57904e+01                1013.1741            98.66609
Dol                          4.78087             7.42808e-02                    13.6975           1.33390
____________________________________________________________________________________________________________________________________________________________
Independent components:
          chemical              disparity                    dual           chemical           molality            log           mg/kgH2O
        composition balance mass                          solution          potential                           molality

C       0.8000000              2.2243e-09               6.88389               4763          6.548e-01           -0.184          7.865e+03
Ca      0.1000000              5.6813e-11            -182.88232            -126525          2.585e-02           -1.588          1.036e+03
Mg      0.1000000              1.3377e-09            -147.42732            -101996          2.585e-02           -1.588          6.283e+02
X       0.1300000             -1.5711e-13               9.26697               6411          1.307e-01           -0.884          0.000e+00
H     112.1119965              5.3163e-08              -5.36014              -3708          1.669e+00            0.222          1.682e+03
O      56.1159983              4.5614e-09             -72.36469             -50065          4.468e-01           -0.350          7.148e+03
e       0.0000e+00             1.9008e-13              -6.19768              -4288

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