Фотоэлектронная спектроскопия. Домашевская Э.П. - 26 стр.

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ВУЗ:

ВГУ | Воронеж

Составители:

Домашевская Э.П.

Рубрика:

Физика

JNWK lZd `_ dZd b \ H`_

ki_dljhkdhibb wg_j]bx k\yab

baf_jyxl hlghkbl_evgh mjh\gy

N_jfb GZ jbk  ihdZaZgZ

ihke_^h\Zl_evghklvkh[ulbcihke_

bhgbaZpbb hklh\gh]h D

mjh\gy

H[hagZq_gby ijbgylu_ \

j_gl]_gh\kdhc b H`_

ki_dljhkdhibb khhlghkylky k

h[hagZq_gbyfb mjh\g_c \ JNWK

ke_^mxsbf h[jZahf .→1s,

→2s, L

→2p

1/2

, L

→2p

3/2

, M

→3s,

→3p

1/2

, M

→3p

3/2

, M

→3d

3/2

→3d

5/2

bl^<^Zgghfijbf_j_

jZkkfZljb\Z_lky bhgbaZpby D-

mjh\gy iZ^Zxsbf nhlhghf,

wg_j]bydhlhjh]hKν^he`gZij_\urZlvwg_j]bxk\yab?

we_dljhgZgZD-

mjh\g_ Dbg_lbq_kdZy wg_j]by?

 nhlhwe_dljhgZ baf_jy_fZy \

ki_dljhf_lj_ \ khhl\_lkl\bb k khhlghr_gb_f Wcgrl_cgZ[m^_l

hij_^_eylvky

?

= h

? +

, (4.1.)

]^_ ?

- wg_j]by k\yab we_dljhgZ \ l\_j^hf l_e_ gZ ^Zgghf mjh\g_ ϕ -

jZ[hlZ\uoh^ZaZ\bkysZyhlijbjh^uh[jZapZbfZl_jbZeZki_dljhf_ljZ

MjZ\g_gb_  ij_^iheZ]Z_l qlh nhlhwe_dljhggZy wfbkkby

ij_^klZ\ey_lkh[hcmijm]bcijhp_kk<uj\Zggucnhlhwe_dljhg\ue_lZ_lba

h[jZapZ ijbh[j_lZy hij_^_e_ggmx ljZ_dlhjbx ih^ ^_ckl\b_f

we_dljhklZlbq_kdh]h beb fZ]gblgh]h ihey ki_dljhf_ljZ b j_]bkljbjm_lky

gZ \uoh^_ ^_l_dlhjhf : Zlhf ihke_ h[jZah\Zgby ^ujdb gZ D-mjh\g_

j_eZdkbjm_laZihegyy wlm^ujdmi_j_oh^hfk\g_rg_]hmjh\gygZijbf_j

 < j_amevlZl_ wlh]h i_j_oh^Z \hagbdZ_l ba[ulhqgZy  wg_j]by jZ\gZy

jZaghklb wg_j]bc?

 b wlZ wg_j]by fh`_l [ulv bkims_gZ eb[h

JbkKo_fZ\ha[m`^_gbybj_eZdkZpbb

ZlhfZijb\ha[m`^_gbbnhlhgZfb

                                                                                       26


                                                bhgbaZpbb hklh\gh]h D-mjh\gy
                                                H[hagZq_gby       ijbgylu_           \
                                                j_gl]_gh\kdhc        b         H`_-
                                                ki_dljhkdhibb    khhlghkylky         k
                                                h[hagZq_gbyfb mjh\g_c \ JNWK
                                                ke_^mxsbf       h[jZahf      .→1s,
JbkKo_fZ\ha[m`^_gbybj_eZdkZpbb
ZlhfZijb\ha[m`^_gbbnhlhgZfb                 L1→2s, L2→2p1/2, L3→2p3/2, M1→3s,
JNWK lZd `_ dZd b \ H`_-                 M2→3p1/2,    M3→3p3/2,       M4→3d3/2,
ki_dljhkdhibb     wg_j]bx    k\yab          M5→3d5/2bl^<^Zgghfijbf_j_
baf_jyxl hlghkbl_evgh mjh\gy                 jZkkfZljb\Z_lky    bhgbaZpby         D-
N_jfb GZ jbk  ihdZaZgZ                 mjh\gy     iZ^Zxsbf        nhlhghf,
ihke_^h\Zl_evghklvkh[ulbcihke_
wg_j]bydhlhjh]hKν^he`gZij_\urZlvwg_j]bxk\yab?k\we_dljhgZgZD-
mjh\g_ Dbg_lbq_kdZy wg_j]by           ?d  nhlhwe_dljhgZ baf_jy_fZy \
ki_dljhf_lj_ \ khhl\_lkl\bb k khhlghr_gb_f Wcgrl_cgZ   [m^_l
hij_^_eylvky


                         ?d= hν - ?k\ + ϕ ,                                 (4.1.)


]^_ ?k\ - wg_j]by k\yab we_dljhgZ \ l\_j^hf l_e_ gZ ^Zgghf mjh\g_ ϕ -
jZ[hlZ\uoh^ZaZ\bkysZyhlijbjh^uh[jZapZbfZl_jbZeZki_dljhf_ljZ
      MjZ\g_gb_       ij_^iheZ]Z_l qlh nhlhwe_dljhggZy wfbkkby
ij_^klZ\ey_lkh[hcmijm]bcijhp_kk

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Фотоэлектронная спектроскопия. Домашевская Э.П. - 26 стр.

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ВУЗ:

Домашевская Э.П.

Физика

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