Фотоэлектронная спектроскопия. Домашевская Э.П. - 29 стр.

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ВГУ | Воронеж

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29
E
i
(1)
- E
i
(2)
= k(q
i
(1)
- q
i
(2)
) + V
i
(1)
- V
i
(2)
beb
∆
E
i
= k
∆
q
i
+
∆
V
i
.
Wlh hagZqZ_l qlh m\_ebq_gb_ wg_j]bb k\yab hklh\gh]h mjh\gy \ i_j\mx
hq_j_^v h[mkeh\e_gh mf_gvr_gb_f iehlghklb \Ze_glguo we_dljhgh\ gZ
Zlhf_Ll_ ihy\e_gb_f gZ Zlhf_Liheh`bl_evgh]h wnn_dlb\gh]h aZjy^Z
GZjbkijb\_^_gj_gl]_ghwe_dljhggucki_dljhklh\gh]h mjh\gyVZahlZ
\ f_lZeehhj]Zgbq_kdhf kh_^bg_gbb Wlhl ijbf_j ohjhrh beexkljbjm_l
hkgh\gu_iheh`_gbyfh^_ebaZjy^h\h]hihl_gpbZeZh[m\_ebq_gbbwg_j]bb
k\yabhklh\gh]hmjh\gykm\_ebq_gb_fkl_i_gbhdbke_gbyZlhfZ
=h\hjy h kf_s_gbb hklh\guo mjh\g_c \ aZ\bkbfhklb hl \_ebqbgu b
agZdZ wnn_dlb\gh]h aZjy^Z gZ g_f ke_^m_l mq_klv lhqghklv \ ijh\_^_gbb
baf_j_gbc wg_j]bc k\yab mjh\g_c GZb[he__ ijhklhc kemqZc gZ[ex^Z_lky
ijbbaf_j_gbyowg_j]bck\yabf_lZeebq_kdh]hh[jZapZdh]^Zf_`^mgbfb
fZl_jbZehfki_dljhf_ljZmklZgZ\eb\Z_lkywe_dljhklZlbq_kdh_jZ\gh\_kb_b
bo mjh\gb N_jfb \ujZ\gb\Zxlky < wlhf kemqZ_ wg_j]by k\yab hklh\gh]h
mjh\gyf_lZeeZbebkieZ\Zhij_^_ey_lkybakhhlghr_gby
(5.3.)
(5.4.)
Jbk
s-
ki_dljZahlZhlljZgk
-
[Co(NH
2
CH
2
CH
2
NH
2
)
2
(NO
2
)
2
]NO
3
                                                                                     29




                      Ei(1) - Ei(2)= k(qi(1) - qi(2)) + Vi(1) - Vi(2)
beb
                                 ∆Ei= k∆qi + ∆Vi .                        (5.3.)


Wlh hagZqZ_l qlh m\_ebq_gb_ wg_j]bb k\yab hklh\gh]h mjh\gy \ i_j\mx
hq_j_^v h[mkeh\e_gh mf_gvr_gb_f iehlghklb \Ze_glguo we_dljhgh\ gZ
Zlhf_ L l_ ihy\e_gb_f gZ Zlhf_ L iheh`bl_evgh]h wnn_dlb\gh]h aZjy^Z
GZjbkijb\_^_gj_gl]_ghwe_dljhggucki_dljhklh\gh]hmjh\gyVZahlZ
\ f_lZeehhj]Zgbq_kdhf kh_^bg_gbb Wlhl ijbf_j ohjhrh beexkljbjm_l
hkgh\gu_iheh`_gbyfh^_ebaZjy^h\h]hihl_gpbZeZh[m\_ebq_gbbwg_j]bb
k\yabhklh\gh]hmjh\gykm\_ebq_gb_fkl_i_gbhdbke_gbyZlhfZ




                                               Jbks-ki_dljZahlZhlljZgk-
                                               [Co(NH2CH2 CH2 NH2)2(NO2)2]NO3

       =h\hjy h kf_s_gbb hklh\guo mjh\g_c \ aZ\bkbfhklb hl \_ebqbgu b
agZdZ wnn_dlb\gh]h aZjy^Z gZ g_f ke_^m_l mq_klv lhqghklv \ ijh\_^_gbb
baf_j_gbc wg_j]bc k\yab mjh\g_c GZb[he__ ijhklhc kemqZc gZ[ex^Z_lky
ijbbaf_j_gbyowg_j]bck\yabf_lZeebq_kdh]hh[jZapZdh]^Zf_`^mgbfb
fZl_jbZehfki_dljhf_ljZmklZgZ\eb\Z_lkywe_dljhklZlbq_kdh_jZ\gh\_kb_b
bo mjh\gb N_jfb \ujZ\gb\Zxlky < wlhf kemqZ_ wg_j]by k\yab hklh\gh]h
mjh\gyf_lZeeZbebkieZ\Zhij_^_ey_lkybakhhlghr_gby


                                                                            (5.4.)

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