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26
LZ[ebpZ
WglZevibyh[jZah\Zgby\w<^_n_dlh\Rhlldb∆
H
S
bNj_gd_ey\
dZlbhgghc∆
H
F
bZgbhgghc∆
H
′
F
ih^j_r_ldZobhgguodjbklZeeh\
DjbklZee
Lbij_
r_ldb
L
F
D
∆G
S
∆
H
F
∆
H
′
F
NaF
NaCl
NaBr
NaI
KF
KCl
KBr
KI
AgCl
AgBr
AgI
CuCl
CaF
2
SrF
2
BaF
2
MgO
CaO
SrO
CeO
2
ThO
2
UO
2
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=_dk
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
=PD
1253
1077
1028
924
1153
1049
1003
1046
728
707
825
695
1633
1463
1553
3073
2845
1703
2223
>3073
2449
2,49
2,26
2,11
1,77
1,92
2,20
2,13
2,00
1,98
-
-
2,27
7,0-8,6
6,9-8,1
6,3-6,9
4-9
5,5-8
5-7
2,0
1,9
~7
3,53
2,88
2,56
2,00
4,27
3,46
3,16
2,73
-
-
0,6-0,8
1,05
6,0
-
-
-
-
-
4,2
5,2
~10
3,39
4,60
4,84
5,14
2,57
3,73
4,17
4,26
-
-
-
-
2,6-2,7
2,2-2,4
1,6-2,0
-
-
-
20
16
~9
26 LZ[ebpZ WglZevibyh[jZah\Zgby \w< ^_n_dlh\Rhlldb∆HSbNj_gd_ey\ dZlbhgghc∆HF bZgbhgghc∆H′F ih^j_r_ldZobhgguodjbklZeeh\ DjbklZee Lbij_ LFD ∆GS ∆HF ∆H′F r_ldb NaF =PD 1253 2,49 3,53 3,39 NaCl =PD 1077 2,26 2,88 4,60 NaBr =PD 1028 2,11 2,56 4,84 NaI =PD 924 1,77 2,00 5,14 KF =PD 1153 1,92 4,27 2,57 KCl =PD 1049 2,20 3,46 3,73 KBr =PD 1003 2,13 3,16 4,17 KI =PD 1046 2,00 2,73 4,26 AgCl =PD 728 1,98 - - AgBr =PD 707 - - - AgI =_dk 825 - 0,6-0,8 - CuCl =PD 695 2,27 1,05 - CaF2 =PD 1633 7,0-8,6 6,0 2,6-2,7 SrF2 =PD 1463 6,9-8,1 - 2,2-2,4 BaF2 =PD 1553 6,3-6,9 - 1,6-2,0 MgO =PD 3073 4-9 - - CaO =PD 2845 5,5-8 - - SrO =PD 1703 5-7 - - CeO2 =PD 2223 2,0 4,2 20 ThO2 =PD >3073 1,9 5,2 16 UO2 =PD 2449 ~7 ~10 ~9