Химическая физика. Черемисин А.А. - 5 стр.

UptoLike

ВУЗ: 

СФУ | Красноярск

Составители: 

Рубрика: 

9
 GZclb l_fi_jZlmjm \hkieZf_g_gby Zahf_lZgZ \ kn_jbq_kdhf khkm^_ jZ^bmkhfkf ijb
^Z\e_gbbffjlklJ_ZdpbyjZaeh`_gbyZahf_lZgZ
CH
3
−
N = N
−
CH
3
→
C
2
H
6
+ N
2
ij_^klZ\ey_lkh[hcj_Zdpbxi_j\h]hihjy^dZkdhgklZglhckdhjhklb
k
= 1,5
⋅
10
15
⋅
e
−
/RT
k
−
1
]^_? ddZefhevb l_ieh\uf wnn_dlhf  ddZefhevDhwnnbpb_gl
l_iehijh\h^ghklbλ
= 1
⋅
10
−
4
ddZeD⋅kf⋅k
 GZclb l_fi_jZlmjm \hkieZf_g_gby]Zah\hc kf_kb kh^_j`Zs_cf_lZgZ dbkehjh^Z b
bg_jlguc jZa[Z\bl_ev \ kn_jbq_kdhf khkm^_ jZ^bmkhfkf ijb Zlfhkn_jghf ^Z\e_gbb
KmffZjgZykdhjhklvhdbke_gbyf_lZgZ
RTE
ea
Tdt
da
−
⋅⋅⋅−=
10
10
9660
,
]^_ Z±dhgp_gljZpby f_lZgZ \ fheve ?  dZefhev L_iehijh\h^ghklv kf_kb⋅
10
−
5
dZeD⋅kf⋅k
 Ihkljhblv ijb[eb`_ggmx aZ\bkbfhklv l_fi_jZlmju ]hj_gby \ j_Zdlhj_ b^_Zevgh]h
kf_rb\Zgby^ey]Zah\hckf_kbkh^_j`Zs_cf_lZgZdbkehjh^ZbZahlijb^Z\e_gbb\
Zlf b l_fi_jZlmj_ LD hl fZkkh\h]h jZkoh^Z kf_kb J_Zdlhj±kn_jZ jZ^bmkZkf
L_iehihl_jyfbij_g_[j_qv
 JZkkqblZlvdjblbq_kdb_ l_ieh\u_ ihlhdb gZ ij_^_e_\hkieZf_g_gby ]hjxq_ckf_kb
kh^_j`Zs_cf_lZgZ  dbkehjh^Z b bg_jlguc jZa[Z\bl_ev ijb ih^`b]Zgbb gZ]j_lhc
ih\_joghklvxijb^Z\e_gbbZlf
Hij_^_eblvjZkij_^_e_gb_l_fi_jZlmj\hnjhgl_eZfbgZjgh]hieZf_gb\ij_^iheh`_gbbqlh
ahgZj_Zdpbbhq_gvmadZyHp_gblvrbjbgmahgu]hj_gbyahguih^h]j_\Z^eyf_^e_ggh]hjys_c
kf_kbf_lZgZ k \ha^mohf ukfk b [ukljh ]hjys_c kf_kb]j_fmqZy kf_kv
H
2
b
O
2
kl_obhf_ljbq_kdh]hkhklZ\Zu fk
 Bkihevamy Zkbfilhlbq_kdmx nhjfmem ^ey kdhjhklb jZkijhkljZg_gby ieZf_gb hp_gblv
kdhjhklvjZkijhkljZg_gby^ey]Zah\hckf_kbkh^_j`Zs_cf_lZgZdbkehjh^ZbZahl
IV. NHJFUDHGLJHEY
aZq_lwdaZf_g
V. MQ?;GHF?LH>BQ?KDH?H;?KI?Q?GB?DMJK:
Kibkhdebl_jZlmju
Hkgh\ghc
1. Dhg^jZlv_\<GGbdblbg??Dbg_lbdZbf_oZgbdZ]ZahnZaguoj_ZdpbcFGZmdZ
558 k
2. WffZgmwevGFDghjj_>DDmjkobfbq_kdhcdbg_lbdb_ba^i_j_jZ[b^hiF<uk
rdheZk
3. A_ev^h\bq Y; ;Zj_g[eZl =B Eb[jh\bq <; FZo\beZ^a_ =F FZl_fZlbq_kdZy l_hjby
]hj_gbyb\aju\ZFGZmdZk
4. Nbabq_kdZyobfby_ba^bkijIh^j_^YB=_jZkbfh\ZFObfbyLk
5. Ijh[e_fuobfbq_kdhcdbg_lbdbHl\j_^<GDhg^jZlv_\FGZmdZk
6. Dmfb]ZgK=hj_gb_FObfbyk
10
>hihegbl_evguc
1. Wcjbg]=EbgK=EbgKFHkgh\uobfbq_kdhcdbg_lbdbFFbjk
2. Dhg^jZlv_\<GGbdblbg?? J_agbdh\:B MfZgkdbcKYL_jfbq_kdb_[bfhe_dmeyjgu_
j_Zdpbb\]ZaZoFGZmdZk
3. NjZgdDZf_g_pdbc >: >bnnmaby b l_iehi_j_^ZqZ \ obfbq_kdhc dbg_lbd_ _ ba^  F
GZmdZk
4. S_lbgdh\?KNbabdZ]hj_gby]Zah\FGZmdZk
5. Ihobe IN ;_ey_\ :N Njheh\ X< Eh]Zq_\ <K Dhjhldh\ :B =hj_gb_
ihjhrdhh[jZaguof_lZeeh\\Zdlb\guokj_^ZoFGZmdZk
6. KhehmobgJBM^Zjgu_\hegub^_lhgZpby\]ZaZoFNbafZl]bak
7. SZedbgDBLjhrbgYD=Zah^bgZfbdZ]hj_gbyFBa^\h:GKKKJk
8. :g^j__\DDL_jfbq_kdh_jZaeh`_gb_b]hj_gb_\aju\qZluo\_s_kl\FGZmdZ
k
9. ObljbgEGNbabdZ]hj_gbyb\aju\ZFBa^\hF=Mk
10.Gh\h`beh\;<G_klZpbhgZjgh_]hj_gb_l\_j^uojZd_lguolhieb\FGZmdZk
11.A_ev^h\bq Y; E_cimgkdbc HB Eb[jh\bq <; L_hjby g_klZpbhgZjgh]h ]hj_gby ihjhoZ
FGZmdZk
12.K[hjgbd\hijhkh\baZ^Zqihnbabq_kdhcobfbb^eykZfhdhgljheyIh^j_^KN;_e_\kdh]h
F<ukrZyrdheZk

Страницы