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UNIT 3
CEMENTITIOUS MATERIALS
Cementations materials include the many products that are mixed with
either water or some other liquid or both to form a cementing paste that may be
formed or molded while plastic but will set into a rigid shape. When sand is
added to the paste, mortar is formed. A combination of coarse and fine
aggregate (sand) added to the paste forms concrete.
TYPES OF CEMENTITIOUS MATERIALS
There are many varieties of cements and numerous ways of classification.
One of the simplest classifications is by the chemical constituent that is
responsible for the setting or hardening of the cement. On this basis, the silicate
and aluminate cements, wherein the setting agents are calcium silicates and
aluminates, constitute the most important group of modern cements. Included in
this group are the portland, aluminous, and natural cements. Limes, wherein the
hardening is due to the conversion of hydroxides to carbonates, were formerly
widely used as the sole cementitious material, but their slow setting and
hardening are not compatible with modern requirements. Hence, their principal
function today is to plasticize the otherwise harsh cements and add resilience to
mortars and stuccoes. Use of limes is beneficial in that their slow setting
promotes healing, the recementing of hairline cracks. Another class of cements
is composed of calcined gypsum and its related products. The gypsum cements
are widely used in interior plaster and for fabrication of boards and blocks; but
the solubility of gypsum prevents its use in construction exposed to any but
extremely dry climates. Oxychloride cements constitute a class of specialty
cements of unusual properties. Their cost prohibits their general use in
competition with the cheaper cements; but for special uses, such as the
production of spark proof floors, they cannot be equaled. Masonry cements or
mortar cements are widely used because of their convenience. While they are,
in general, mixtures of one of more of the above-mentioned cements with some
admixtures, they deserve special consideration because of their economies.
Other cementitious materials, such as polymers, fly ash, and silica fume, may
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